Hello.
Yes you can auto-start apps when your liberkey starts (or when closes).
Open the Autorun menu (Liberkey Tools => Configuration => Autorun ) Check the box Enable Autorun.
Normally the box When Liberkey starts is already checked.
Drag and drop the app(s) you want to start automatically from one of the menu in the main interface of your Liberkey like this :
When you have added the apps you want, you can order them with the button at the rigth of the windows. (When you move slowly over them, a contextual help function explains).
On top of the window you can specify the time before the autorun and time between each app started.
Enjoys.
JP4U