Hello cujobr.
You wrote :
How Can I set autorun in liberkey configuration??
For while, I do it manually.
For the app you want autorun right click on it choose Shortcut properties, advanced and you find at the bottom of the windows the options for launch it (Never ; Always on startup ; On startup if not already running ; On shutdown ; On shutdown if not already running).
If you have many apps to run, in Liberkey Tools => Liberkey configuration => Autorun you can choose the order to launch them,the time before launch and between two launches.
(Sorry, but at these time you can't add apps in these Autorun configuration's windows directly by drag and drop or with a button. I hope it will be possible in the future).
JP4U